Synthesis and structure of two octahedral molybdenum chloride sulfide clusters

Synthesis and structure of two octahedral molybdenum chloride sulfide clusters [electronic resource]

A preparation for chloride sulfide Mo₆X₈ clusters has been devised which employs substitution by sulfide into the Mo₆Cl₈/sup 4 +/ cluster. The Mo₆Cl₇S/sup 3 +/ cluster has been isolated in the two compounds (C₅H₅NH)₃((Mo₆Cl₇S)Cl₆) x 3(C₅H₅NH)Cl and (C₅H₅NH)₃((Mo₆Cl₇S)Cl₆). The structures of both com...

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Bibliographic Details
Online Access: Online Access
Corporate Author: Ames Laboratory (Researcher)
Format: Government Document Electronic eBook
Language:English
Published: Ames, Iowa : Oak Ridge, Tenn. : Ames Laboratory ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 1980.
Subjects:
X-ray Diffraction.
Sulfides.
Scattering.
Chlorine Compounds.
Organic Compounds.
Amines.
Infrared Spectra.
Pyridinium Compounds.
Chemical Preparation.
Transition Element Compounds.
Sulfur Compounds.
Molecular Structure.
Spectra.
Molybdenum Chlorides.
Halogen Compounds.
Halides.
Complexes.
Quaternary Compounds.
Diffraction.
Crystal Structure.
Chlorides.
Heterocyclic Compounds.
Organic Nitrogen Compounds.
Azines.
Synthesis.
Pyridines.
Molybdenum Compounds.
Coherent Scattering.
Ammonium Compounds.
Molybdenum Sulfides.
Molybdenum Complexes.
Transition Element Complexes.
Chalcogenides.
Inorganic, Organic, Physical And Analytical Chemistry.

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Call Number: E 1.99:is-t-881
E 1.99:is-t-881 Available

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