Reactivity patterns of transition metal hydrides and alkyls

Reactivity patterns of transition metal hydrides and alkyls [electronic resource]

The complex PPN⁺ CpV(CO)₃H⁻ (Cp=eta⁵-C₅H₅ and PPN = (Ph₃P)₂) was prepared in 70% yield and its physical properties and chemical reactions investigated. PPN⁺ CpV(CO)₃H⁻ reacts with a wide range of organic halides. The organometallic products of these reactions are the vanadium halides PPN⁺(CpV(C)₃X)⁻...

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Bibliographic Details
Online Access: Online Access
Corporate Authors: California Institute of Technology (Researcher), Lawrence Berkeley National Laboratory (Researcher)
Format: Government Document Electronic eBook
Language:English
Published: Berkeley, Calif. : Oak Ridge, Tenn. : Lawrence Berkeley National Laboratory ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 1979.
Subjects:
Kinetics.
Organic Phosphorus Compounds.
Organic Compounds.
Carbonyls.
Cycloalkenes.
Rhodium Complexes.
Cyclopentadiene.
Boron Compounds.
Organic Halogen Compounds.
Chemical Reaction Kinetics.
Hydrides.
Cobalt Complexes.
Vanadium Complexes.
Complexes.
Chemical Properties.
Alkylation.
Organometallic Compounds.
Alkenes.
Borohydrides.
Polyenes.
Dienes.
Phosphines.
Molybdenum Complexes.
Chemical Reactions.
Phosphorus Compounds.
Transition Element Complexes.
Reduction.
Reaction Kinetics.
Hydrocarbons.
Hydrogen Compounds.
Inorganic, Organic, Physical And Analytical Chemistry.

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Call Number: E 1.99:lbl-10214
E 1.99:lbl-10214 Available

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