1. Mono([8]annulene)Uranium(4) half-sandwich complexes, 2. Novel syntheses of symmetrically substituted cyclooctatetetraenes

1. Mono([8]annulene)Uranium(4) half-sandwich complexes, 2. Novel syntheses of symmetrically substituted cyclooctatetetraenes [electronic resource]

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A reproducible, high-yield synthesis of mono([8]annulene)uranium(4)dichloride (1) is reported, along with the X-ray crystal structural of the bis(pyridine) adduct. Metathesis reactions of the half-sandwich complex 1 with a variety of simple alkyl and alkoxy reagents failed to generate any isolable m...

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Bibliographic Details
Online Access: Online Access (via OSTI)
Corporate Author: Lawrence Livermore National Laboratory (Researcher)
Format: Government Document Thesis Electronic eBook
Language:English
Published: Washington, D.C. : Oak Ridge, Tenn. : United States. Department of Energy. Office of Basic Energy Sciences ; distributed by the Office of Scientific and Technical Information, U.S. Department of Energy, 1991.
Subjects:
Uranium Complexes.
Chemical Preparation.
Polyenes.
Organometallic Compounds.
Structural Chemical Analysis.
X-Ray Diffraction.
Bond Lengths.
Inorganic, Organic, Physical And Analytical Chemistry.
Radiation Chemistry, Radiochemistry, And Nuclear Chemistry.

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Call Number: E 1.99:lbl--31459
E 1.99:lbl--31459 Available

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