Advanced organic chemistry / Deepa Sharma.
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Full Text (via ProQuest) |
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| Format: | eBook |
| Language: | English |
| Published: |
Tunbridge Wells :
New Academic Science,
©2012.
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Table of Contents:
- ""Cover ""; ""Preface""; ""Acknowledgements""; ""Contents""; ""Section-I Fundamentals of Organic Chemistry ""; ""Chapter 1 Atomic Bonding ""; ""1.1 Introduction ""; ""1.2 Valence Bond Theory ""; ""1.3 Molecular Orbital Theory (MOT) ""; ""1.3.1 Formation of Bonding Molecular Orbital (Additive Overlapping of Two Atomic Orbitals) ""; ""1.3.2 Formation of Antibonding Molecular Orbital (ABMO)(Subtractive Overlapping of Two Atomic Orbitals)""; ""1.3.3 Rules for Linear Combination of Atomic Orbitals""; ""1.3.4 Rules for Filling up of Molecular Orbitals""; ""1.3.5 MO Diagram""
- ""1.3.6 Bond Order or Bond Multiplicity""""1.3.7 Difference between Atomic Orbitals and Molecular Orbitals""; ""1.3.8 Similarities between Atomic Orbitals and Molecular Orbitals""; ""1.4 VSEPR Theory ""; ""1.4.1 Postulates of VSEPR Theory""; ""1.5 Metallic Crystal ""; ""1.5.1 Factors Favouring the Formation of Metallic Bond""; ""1.5.2 Nature of Metallic Bond""; ""1.5.3 Some of the Physical Properties of Metals and their Explanation on the Basis of Electron-gas Theory ""; ""1.6 Hydrogen Bond ""; ""1.6.1 What is Hydrogen Bond?""; ""1.6.2 Types of Hydrogen Bonding""
- ""1.6.3 Nature and Formation of Hydrogen Bond""""1.6.4 Conditions for the Formation of Hydrogen Bond""; ""1.6.5 Strength of H-bond""; ""1.6.6 Effect of Hydrogen Bonding on the Physical Properties of the Compounds Containing Hydrogen Bonds ""; ""Chapter 2 Stereochemistry ""; ""2.1 Isomerism ""; ""2.1.1 Structural Isomerism""; ""2.2 Stereoisomerism ""; ""2.2.1 General Terms Encountered in Stereochemistry or Causes of Optical Isomerism ""; ""2.3 Optical Isomerism and Chirality ""; ""2.3.1 Optical Activity""; ""2.3.2 The Polarimeter""; ""2.3.3 Calculation of Number of Optical Isomers""
- ""2.4 Compounds Containing More Than One Chiral Centres """"2.5 Specific Configuration for Compounds Containing More than one Chiral Centre ""; ""2.6 Geometrical Isomerism or CIS-Trans Isomerism ""; ""2.7 Racemization ""; ""2.8 Walden Inversion ""; ""2.9 To Assign 'E-Z' Configuration and 'R-S' Configuration on the Basis of Sequence Rule ""; ""2.10 Conversion of 3-Dimensional Structures to Fischer Projection Formula ""; ""2.11 Optically Active Compounds Without Chiral Centre ""; ""2.11.1 Chirality in Allenes""; ""2.11.2 Chirality in Spirans""; ""2.11.3 Chirality in Biphenyls""
- ""2.12 Conformational Analysis """"2.12.1 Conformers of Ethane""; ""2.12.2 Conformations of n-Butane""; ""2.12.3 Conformations of 1,2-Dichloro Ethane""; ""Chapter 3 Reaction Intermediates and Factors Affecting Reactivity ""; ""3.1 Carbonium Ion or Carbocations ""; ""3.1.1 Classification of Carbonium Ions""; ""3.1.2 Formation of Carbonium Ions""; ""3.1.3 Order of Stability of Carbonium Ions""; ""3.1.4 Structure of Carbonium Ion""; ""3.2 Carbanions ""; ""3.2.1 Classification of Carbanions""; ""3.2.2 Structure of Carbanions""; ""3.2.3 Stability of Carbanions""