Radiolytic gas production from tritiated water sorbed on molecular sieve [electronic resource]

Samples of 4 A molecular sieve containing 5, 20, and 35 wt % H/sub 2/O were irradiated in sealed containers in a /sup 60/Co ..gamma..-ray source. A previous study showed that the effects of tritium ..beta..-radiolysis can be closely simulated by /sup 60/Co ..gamma..-radiolysis. During radiolysis, th...

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Bibliographic Details
Online Access: Online Access (via OSTI)
Format: Government Document Electronic eBook
Language:English
Published: Oak Ridge, Tenn. : distributed by the Office of Scientific and Technical Information, U.S. Department of Energy, 1977.
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MARC

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245 0 0 |a Radiolytic gas production from tritiated water sorbed on molecular sieve  |h [electronic resource] 
260 |a Oak Ridge, Tenn. :  |b distributed by the Office of Scientific and Technical Information, U.S. Department of Energy,  |c 1977. 
300 |a Pages: 8 :  |b digital, PDF file. 
336 |a text  |b txt  |2 rdacontent. 
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338 |a online resource  |b cr  |2 rdacarrier. 
500 |a Published through SciTech Connect. 
500 |a 07/12/1977. 
500 |a "dpst-77-375" 
500 |a Du Pont de Nemours (E.I.) and Co., Aiken, S.C. (USA). Savannah River Lab. 
520 3 |a Samples of 4 A molecular sieve containing 5, 20, and 35 wt % H/sub 2/O were irradiated in sealed containers in a /sup 60/Co ..gamma..-ray source. A previous study showed that the effects of tritium ..beta..-radiolysis can be closely simulated by /sup 60/Co ..gamma..-radiolysis. During radiolysis, the pressure of the containers was monitored, and the gas composition was determined. Results indicated that H/sub 2/ was the only gas produced. O/sub 2/ in air sealed in the container was depleted by radiolysis. Final pressures depended on the amount of tritium and H/sub 2/O present. At low tritium and low water contents, the final pressures were low (15 psi for 7 curies tritium/g sieve and 20 wt % H/sub 2/O). The maximum initial 100-eV yield for H/sub 2/ was 0.3 molecules/100-eV. Based on these results, TA 2-880 concerning tritium waste storage can be revised to permit containers of tritiated water sorbed on molecular sieve to be accepted for safe storage. 
536 |b EY-76-C-01-0009. 
650 7 |a Radioactive Waste Storage.  |2 local. 
650 7 |a Tritium Oxides.  |2 local. 
650 7 |a Autoradiolysis.  |2 local. 
650 7 |a Adsorption.  |2 local. 
650 7 |a Cobalt 60.  |2 local. 
650 7 |a Gamma Radiation.  |2 local. 
650 7 |a Gases.  |2 local. 
650 7 |a Hydrogen.  |2 local. 
650 7 |a Molecular Sieves.  |2 local. 
650 7 |a Oxygen.  |2 local. 
650 7 |a Production.  |2 local. 
650 7 |a Radiation Sources.  |2 local. 
650 7 |a Adsorbents.  |2 local. 
650 7 |a Autolysis.  |2 local. 
650 7 |a Beta Decay Radioisotopes.  |2 local. 
650 7 |a Beta-Minus Decay Radioisotopes.  |2 local. 
650 7 |a Chemical Radiation Effects.  |2 local. 
650 7 |a Chemical Reactions.  |2 local. 
650 7 |a Chemistry.  |2 local. 
650 7 |a Cobalt Isotopes.  |2 local. 
650 7 |a Cryogenic Fluids.  |2 local. 
650 7 |a Decomposition.  |2 local. 
650 7 |a Electromagnetic Radiation.  |2 local. 
650 7 |a Elements.  |2 local. 
650 7 |a Fluids.  |2 local. 
650 7 |a Intermediate Mass Nuclei.  |2 local. 
650 7 |a Internal Conversion Radioisotopes.  |2 local. 
650 7 |a Ionizing Radiations.  |2 local. 
650 7 |a Isomeric Transition Isotopes.  |2 local. 
650 7 |a Isotopes.  |2 local. 
650 7 |a Labelled Compounds.  |2 local. 
650 7 |a Management.  |2 local. 
650 7 |a Minutes Living Radioisotopes.  |2 local. 
650 7 |a Nonmetals.  |2 local. 
650 7 |a Nuclei.  |2 local. 
650 7 |a Odd-Odd Nuclei.  |2 local. 
650 7 |a Radiation Chemistry.  |2 local. 
650 7 |a Radiation Effects.  |2 local. 
650 7 |a Radiations.  |2 local. 
650 7 |a Radioactive Materials.  |2 local. 
650 7 |a Radioisotopes.  |2 local. 
650 7 |a Radiolysis.  |2 local. 
650 7 |a Sorption.  |2 local. 
650 7 |a Storage.  |2 local. 
650 7 |a Tritium Compounds.  |2 local. 
650 7 |a Waste Management.  |2 local. 
650 7 |a Waste Storage.  |2 local. 
650 7 |a Years Living Radioisotopes.  |2 local. 
650 7 |a Management Of Radioactive And Non-Radioactive Wastes From Nuclear Facilities.  |2 edbsc. 
650 7 |a Radiation Chemistry, Radiochemistry, And Nuclear Chemistry.  |2 edbsc. 
710 1 |a United States.  |b Department of Energy.  |b Office of Scientific and Technical Information.  |4 dst. 
856 4 0 |u http://www.osti.gov/scitech/biblio/5359358  |z Online Access (via OSTI) 
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