Long-term lithium-ion battery performance improvement via ultraviolet light treatment of the graphite anode [electronic resource]

Effects of ultraviolet (UV) light on dried graphite anodes were investigated in terms of the cycle life of lithium ion batteries. The time variations for the UV treatment were 0 (no treatment), 20, 40, and 60 minutes. UV-light-treated graphite anodes were assembled for cycle life tests in pouch cell...

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Bibliographic Details
Online Access: Online Access (via OSTI)
Corporate Author: Oak Ridge National Laboratory (Researcher)
Format: Government Document Electronic eBook
Language:English
Published: Washington, D.C. : Oak Ridge, Tenn. : United States. Department of Energy. Office of Energy Efficiency and Renewable Energy ; distributed by the Office of Scientific and Technical Information, U.S. Department of Energy, 2016.
Subjects:

MARC

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245 0 0 |a Long-term lithium-ion battery performance improvement via ultraviolet light treatment of the graphite anode  |h [electronic resource] 
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500 |a Journal of the Electrochemical Society 163 14 ISSN 0013-4651 AM. 
500 |a Seong Jin An; Jianlin Li; Yangping Sheng; Claus Daniel; David L. Wood, III. 
520 3 |a Effects of ultraviolet (UV) light on dried graphite anodes were investigated in terms of the cycle life of lithium ion batteries. The time variations for the UV treatment were 0 (no treatment), 20, 40, and 60 minutes. UV-light-treated graphite anodes were assembled for cycle life tests in pouch cells with pristine Li<sub>1.02</sub>Ni<sub>0.50</sub>Mn<sub>0.29</sub>Co<sub>0.19</sub>O<sub>2</sub> (NMC 532) cathodes. UV treatment for 40 minutes resulted in the highest capacity retention and the lowest resistance after the cycle life testing. X-ray photoelectron spectroscopy (XPS) and contact angle measurements on the graphite anodes showed changes in surface chemistry and wetting after the UV treatment. XPS also showed increases in solvent products and decreases in salt products on the SEI surface when UV-treated anodes were used. In conclusion, the thickness of the surface films and their compositions on the anodes and cathodes were also estimated using survey scans and snapshots from XPS depth profiles. 
520 0 |a Ultraviolet (Uv) Light; Electrode; Cycle Life; Xps; Impedance; Battery; Capacity Fade; Contact Angle; Electrochemistry; Impedance. 
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