Behavior of americium in aqueous carbonate systems [electronic resource]

The solubilities of crystalline Am(OH)₃ and AmOHCO₃ were measured at 25°C in aqueous solutions of 0.1 M NaClO₄ by determination of the solution concentrations of Am. Prior to use in the measurements, the solid materials were characterized by their x-ray powder diffraction patterns. The solubility pr...

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Bibliographic Details
Online Access: Online Access
Corporate Authors: Lawrence Berkeley Laboratory (Researcher), Lawrence Berkeley National Laboratory (Researcher)
Format: Government Document Electronic eBook
Language:English
Published: Berkeley, Calif. : Oak Ridge, Tenn. : Lawrence Berkeley National Laboratory ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 1983.
Subjects:

MARC

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245 0 0 |a Behavior of americium in aqueous carbonate systems  |h [electronic resource] 
260 |a Berkeley, Calif. :  |b Lawrence Berkeley National Laboratory ;  |a Oak Ridge, Tenn. :  |b distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy,  |c 1983. 
300 |a Pages: 10 :  |b digital, PDF file. 
336 |a text  |b txt  |2 rdacontent. 
337 |a computer  |b c  |2 rdamedia. 
338 |a online resource  |b cr  |2 rdacarrier. 
500 |a Published through the Information Bridge: DOE Scientific and Technical Information. 
500 |a 11/01/1983. 
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500 |a "DE84004882" 
500 |a Materials Research Society annual meeting, Boston, MA, USA, 14 Nov 1983. 
500 |a Silva, R.J. 
520 3 |a The solubilities of crystalline Am(OH)₃ and AmOHCO₃ were measured at 25°C in aqueous solutions of 0.1 M NaClO₄ by determination of the solution concentrations of Am. Prior to use in the measurements, the solid materials were characterized by their x-ray powder diffraction patterns. The solubility product quotients were calculated from the experimental data. The hydrolysis quotients of Am/sup 3 +/ were also estimated from the hydroxide solubility data. Using the thermodynamic data derived from these experiments and the recently reported formation constants for the Am/sup 3 +/ carbonate complexes, the solid phases and concentrations of solution species of americium in several aqueous carbonate systems were calculated using the computer code MINEQL. 20 references, 1 figure, 1 table. 
536 |b AC03-76SF00098. 
650 7 |a Information.  |2 local. 
650 7 |a Experimental Data.  |2 local. 
650 7 |a Solvolysis.  |2 local. 
650 7 |a Chlorine Compounds.  |2 local. 
650 7 |a Organic Compounds.  |2 local. 
650 7 |a Hydroxides.  |2 local. 
650 7 |a Sodium Compounds.  |2 local. 
650 7 |a Americium Carbonates.  |2 local. 
650 7 |a Actinide Compounds.  |2 local. 
650 7 |a Oxygen Compounds.  |2 local. 
650 7 |a Carbonates.  |2 local. 
650 7 |a Carbon Compounds.  |2 local. 
650 7 |a Hydrolysis.  |2 local. 
650 7 |a Halogen Compounds.  |2 local. 
650 7 |a Americium Compounds.  |2 local. 
650 7 |a Americium Hydroxides.  |2 local. 
650 7 |a Transuranium Compounds.  |2 local. 
650 7 |a Numerical Data.  |2 local. 
650 7 |a Lysis.  |2 local. 
650 7 |a Solubility.  |2 local. 
650 7 |a Hydroxy Compounds.  |2 local. 
650 7 |a Sodium Perchlorates.  |2 local. 
650 7 |a Decomposition.  |2 local. 
650 7 |a Perchlorates.  |2 local. 
650 7 |a Transplutonium Compounds.  |2 local. 
650 7 |a Chemical Reactions.  |2 local. 
650 7 |a Alkali Metal Compounds.  |2 local. 
650 7 |a Data.  |2 local. 
650 7 |a Hydrogen Compounds.  |2 local. 
650 7 |a Management Of Radioactive And Non-radioactive Wastes From Nuclear Facilities.  |2 edbsc. 
650 7 |a Nuclear Fuel Cycle And Fuel Materials.  |2 edbsc. 
650 7 |a Radiation Chemistry, Radiochemistry, And Nuclear Chemistry.  |2 edbsc. 
710 2 |a Lawrence Berkeley Laboratory.  |4 res. 
710 2 |a Lawrence Berkeley National Laboratory.  |4 res. 
710 1 |a United States.  |b Department of Energy.  |b Office of Scientific and Technical Information.  |4 dst. 
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