Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate [electronic resource]

This research was intended to provide the scientific foundation upon which the feasibility of liquid-liquid extraction chemistry for bulk reduction of the volume of high-activity tank waste can be evaluated. Primary focus has been on sodium hydroxide separation, with potential Hanford application. V...

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Bibliographic Details
Online Access: Online Access
Corporate Authors: University of North Texas (Researcher), United States. Department of Energy. Idaho Operations Office (Researcher)
Format: Government Document Electronic eBook
Language:English
Published: Idaho Falls, Idaho : Oak Ridge, Tenn. : United States. Dept. of Energy. Idaho Operations Office. ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2004.
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Summary:This research was intended to provide the scientific foundation upon which the feasibility of liquid-liquid extraction chemistry for bulk reduction of the volume of high-activity tank waste can be evaluated. Primary focus has been on sodium hydroxide separation, with potential Hanford application. Value in sodium hydroxide separation can potentially be found in alternative flowsheets for treatment and disposal of low-activity salt waste. Additional value can be expected in recycle of sodium hydroxide for use in waste retrieval and sludge washing, whereupon additions of fresh sodium hydroxide to the waste can be avoided. Potential savings are large both because of the huge cost of vitrification of the low-activity waste stream and because volume reduction of high-activity wastes could obviate construction of costly new tanks. Toward these ends, the conceptual development begun in the original proposal was extended with the formulation of eight fundamental approaches that could be undertaken for extraction of sodium hydroxide.
Item Description:Published through the Information Bridge: DOE Scientific and Technical Information.
06/08/2004.
"doe/er/14936"
Bruce A. Moyer; Peter V. Bonnesen; Alan P. Marchand; Jeffrey C. Bryan; Tamara J. Haverlock.
(US)
Physical Description:vp. : digital, PDF file.