Kinetics and mechanisms of the reactions of alkyl radicals with oxygen and with complexes of Co(III), Ru(III), and Ni(III)

Kinetics and mechanisms of the reactions of alkyl radicals with oxygen and with complexes of Co(III), Ru(III), and Ni(III) [electronic resource]

The kinetics of the reactions of C₂H₅ radical with Co(NH₃)₅X{sup 2+}, Ru(NH₃)₅X{sup 2+}, and Co(dmgH)₂ (X) (Y) (X = Br, Cl, N₃, SCN; Y = H₂O, CH₃CN) complexes were studied using laser flash photolysis of ethylcobalt complexes. The kinetics were obtained by the kinetic probe method. Some relative rat...

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Bibliographic Details
Online Access: Online Access
Corporate Author: Ames Laboratory (Researcher)
Format: Government Document Electronic eBook
Language:English
Published: Washington, D.C : Oak Ridge, Tenn. : United States. Dept. of Energy. Office of Energy Research ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 1990.
Subjects:
Kinetics.
Photochemical Reactions.
Organic Compounds.
Chlorine Compounds.
Drugs.
Iridium Compounds.
Transition Element Compounds.
Chemical Reaction Kinetics.
Bromine Compounds.
Radicals.
Thiocyanates.
Hormone Antagonists.
Photolysis.
Elements.
Oxygen.
Halogen Compounds.
Cobalt Complexes.
Halides.
Complexes.
Yields.
Nonmetals.
Ruthenium Complexes.
Antithyroid Drugs.
Organic Nitrogen Compounds.
Chlorides.
Decomposition.
Nickel Complexes.
Refractory Metal Compounds.
Iridium Chlorides.
Chemical Reactions.
Nitriles.
Transition Element Complexes.
Reaction Kinetics.
Organic Sulfur Compounds.
Chemical Reaction Yield.
Acetonitrile.
Alkyl Radicals.
Ethyl Radicals.
Carbonic Acid Derivatives.
Inorganic, Organic, Physical And Analytical Chemistry.

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Call Number: E 1.99:is-t-1492
E 1.99:is-t-1492 Available

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