Measurement of alkali-vapor emission from pressurized fluidized-bed combustion of Illinois coals [electronic resource]
Two Illinois Herrin No. 6 coals and one Illinois Springfield No. 5 coal were separately combusted in a laboratory-scale (15-cm dia) pressurized fluidized-bed combustor (PFBC) combined with an alkali sorber. These coals were combusted in a fluidized bed of Tymochtee dolomite at temperatures ranging f...
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Online Access |
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Corporate Author: | |
Format: | Government Document Electronic eBook |
Language: | English |
Published: |
Washington, D.C. : Oak Ridge, Tenn. :
United States. Department of Energy ; distributed by the Office of Scientific and Technical Information, U.S. Department of Energy,
1993.
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Summary: | Two Illinois Herrin No. 6 coals and one Illinois Springfield No. 5 coal were separately combusted in a laboratory-scale (15-cm dia) pressurized fluidized-bed combustor (PFBC) combined with an alkali sorber. These coals were combusted in a fluidized bed of Tymochtee dolomite at temperatures ranging from 910 to 950[degree]C and a system pressure of 9.2 atm absolute. Alkali-vapor emission (Na and K) in the PFBC flue gas was determined by the analytical activated-bauxite sorber bed technique developed at Argonne National Laboratory. The test results showed that sodium is the major alkali-vapor species present in the PFBC flue gas, and that the level of sodium-vapor emission increases linearly with both Na and Cl contents in the coals. This suggests that the sodium-vapor emission results from direct vaporization of NaCl present in the coals. The measured alkali-vapor concentration (Na + K), 67 to 190 ppbW, is more than 2.5 times greater than the allowable alkali limit of 24 ppb for an industrial gas turbine. Combusting these coals in a PFBC for power generation may require developing a method to control alkali vapors. |
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Item Description: | Published through SciTech Connect. 01/01/1993. "anl/cmt/cp-76154" " conf-930521--6" "DE93010660" 12. international conference on fluidized-bed combustion, San Diego, CA (United States), 8-13 May 1993. Lee, S.H.D.; Banerjee, D.D.; Swift, W.M.; Teats, F.G. |
Physical Description: | Pages: (11 p) : digital, PDF file. |