Lithium compounds in organic synthesis : from fundamentals to applications / edited by Renzo Luisi and Vito Capriati.
This unique book covers fundamentals of organolithium compounds and gives a comprehensive overview of the latest synthetic advances and developments in the field. Part I covers computational and spectroscopic aspects as well as structure-reactivity relationships of organolithiums, whereas Part II de...
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Full Text (via Wiley) |
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| Other Authors: | , |
| Format: | eBook |
| Language: | German English |
| Published: |
Weinheim, Germany :
Wiley-VCH Verlag,
2014.
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| Subjects: |
MARC
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| 245 | 0 | 0 | |a Lithium compounds in organic synthesis : |b from fundamentals to applications / |c edited by Renzo Luisi and Vito Capriati. |
| 264 | 1 | |a Weinheim, Germany : |b Wiley-VCH Verlag, |c 2014. | |
| 264 | 4 | |c ©2014. | |
| 300 | |a 1 online resource (xxiv, 545 pages) : |b illustrations. | ||
| 336 | |a text |b txt |2 rdacontent. | ||
| 337 | |a computer |b c |2 rdamedia. | ||
| 338 | |a online resource |b cr |2 rdacarrier. | ||
| 504 | |a Includes bibliographical references at the end of each chapters and index. | ||
| 505 | 0 | |a Lithium Compounds in Organic Synthesis; Contents; List of Contributors; Foreword; Preface; Part I New Structural Aspects of Lithium Compounds; Chapter 1 Structure-Reactivity Relationship in Organolithium Compounds; 1.1 Structural Principles in Organolithium Compounds; 1.2 Donor-Base-Free Structures; 1.2.1 Tetramers; 1.2.2 Hexamers; 1.2.3 Comparison of [Me3SiCH2Li]6 and [n-BuLi]6; 1.3 Disaggregation with Lewis Bases; 1.3.1 Tetramers of Alkyllithium Compounds; 1.3.2 Asymmetric Aggregates of [Me3SiCH2Li] (4); 1.3.3 An Octameric Aggregate of [Me3SiCH2Li]6. | |
| 505 | 8 | |a 1.4 Donor-Base-Induced Dimers and Monomers1.4.1 Alkyllithium and Trimethylsilylmethyllithium Compounds; 1.4.2 PMDETA Aggregated Monomers; 1.5 Heterobimetallic Organolithium Compounds; 1.6 Conclusion and Outlook; References; Further Reading; Chapter 2 Computational Perspectives on Organolithiums; 2.1 Introduction; 2.2 The Nature of Bonds to Lithium; 2.3 Aggregation of Lithium Organic Compounds; 2.4 Solvation Effects; 2.5 Lithium Alkoxides and Lithium Amides; 2.6 Computational Studies on Various Organolithium Applications; 2.7 Conclusion and Outlook; References; Further Reading. | |
| 505 | 8 | |a Chapter 3 Spectroscopic Advances in Organolithium Reactivity: The Contribution of Rapid-Injection NMR (RINMR)3.1 Introduction; 3.2 The Curtin-Hammett Principle; 3.3 Organolithium NMR; 3.4 Features of RINMR; 3.4.1 Brief History; 3.4.2 Apparatus Descriptions and Rapidity of Acquisition; 3.4.3 Temperature Range and Control; 3.4.4 Volume Accuracy of Injection; 3.5 Use of RINMR to Study Organometallic Reactions; 3.5.1 n-Butyllithium Aggregate Reactivity (1985); 3.5.2 Magnesium Chelates in Carbonyl Additions (1987/1990); 3.5.3 Lithium Enolate Aldol (1992) | |
| 505 | 8 | |a 3.5.4 Alkyllithium Polymerization (1995/1999)3.5.5 Tin Transmetallation (2007); 3.5.6 Cuprates (2002-Present); 3.5.7 n-BuLi Aggregate Reactivity Revisited (2007); 3.5.8 Tris(trimethylsilyl)methyllithium (2008/2009); 3.5.9 Enolization and Lithium Aldol (2011); 3.6 Conclusion and Outlook; References; Further Reading; Chapter 4 Spectroscopic Advances in Structural Lithium Chemistry: Diffusion-Ordered Spectroscopy and Solid-State NMR; 4.1 General Introduction; 4.2 Application of Solution NMR to the Structural Characterization of Organolithium Compounds; 4.2.1 Diffusion NMR Measurement Methods. | |
| 505 | 8 | |a 4.2.1.1 Pulsed Field Gradient Spin Echo (PFGSE)4.2.1.2 From the First to the Second Dimension: DOSY NMR Experiment; 4.2.2 DOSY Application to the Structural Analysis of Organolithium Compounds; 4.2.2.1 Structure of the Mixed Methyllithium/Lithium Chloride Aggregate; 4.2.2.2 Structure of a Lithium Phosphido-Borane; 4.2.2.3 Structure of Lithium Zincate; 4.2.3 Conclusion; 4.3 Solid-State NMR; 4.3.1 Basic Principles; 4.3.1.1 Homo and Heteronuclear Dipole-Dipole Couplings (D: Dipole-Dipole); 4.3.1.2 Chemical Shift Anisotropy (CSA); 4.3.1.3 Quadrupolar Interactions for Nuclei with I<1/2 (Q) | |
| 520 | |a This unique book covers fundamentals of organolithium compounds and gives a comprehensive overview of the latest synthetic advances and developments in the field. Part I covers computational and spectroscopic aspects as well as structure-reactivity relationships of organolithiums, whereas Part II deals with new lithium-based synthetic methodologies as well as novel synthetic applications of functionalized lithium compounds. A useful resource for newcomers and active researchers involved in organic synthesis, whether working in academia or industry! | ||
| 546 | |a English. | ||
| 588 | 0 | |a Online resource; title from PDF title page (ebrary, viewed March 20, 2014) | |
| 650 | 0 | |a Cyclic compounds. |0 http://id.loc.gov/authorities/subjects/sh85035066. | |
| 650 | 0 | |a Lithium compounds. |0 http://id.loc.gov/authorities/subjects/sh98005205. | |
| 650 | 0 | |a Organic compounds |x Synthesis. |0 http://id.loc.gov/authorities/subjects/sh85023025. | |
| 650 | 7 | |a Cyclic compounds. |2 fast |0 (OCoLC)fst00885840. | |
| 650 | 7 | |a Lithium compounds. |2 fast |0 (OCoLC)fst01000233. | |
| 650 | 7 | |a Organic compounds |x Synthesis. |2 fast |0 (OCoLC)fst01047668. | |
| 700 | 1 | |a Luisi, Renzo, |e editor. |0 http://id.loc.gov/authorities/names/nb2014008882 |1 http://isni.org/isni/0000000433657156. | |
| 700 | 1 | |a Capriati, Vito, |e editor. |0 http://id.loc.gov/authorities/names/nb2014008883 |1 http://isni.org/isni/0000000435379276. | |
| 776 | 0 | 8 | |i Print version: |t Lithium compounds in organic synthesis. |d Weinheim : Wiley-VCH 2014 |z 3527333436 |w (OCoLC)876346431. |
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