NMR and MRI of electrochemical energy storage materials and devices /

NMR and MRI of electrochemical energy storage materials and devices / editors: Yong Yang, Riqiang Fu, Hua Huo.

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The aim of this book is to introduce the use of NMR and MRI methods for investigating electrochemical storage materials and devices to help both NMR spectroscopists entering the field of batteries and battery specialists seeking diagnostic methods for material and device degradation.

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Bibliographic Details
Online Access: Full Text (via Knovel)
Other Authors: Yang, Yong (Editor), Fu, Riqiang (Editor), Huo, Hua (Editor)
Format: eBook
Language:English
Published: Cambridge, United Kingdom : Royal Society of Chemistry, [2021]
Series:New developments in NMR ; no. 25.
Subjects:
Energy storage.
Nuclear magnetic resonance.
Table of Contents:
  • Intro
  • Half Title
  • Series
  • Title
  • Copyright
  • Preface
  • List of Abbreviations
  • Contents
  • Part I Physical backgrounds and experimental methodology
  • Chapter 1 NMR Principles of Paramagnetic Materials
  • 1.1 Spin Interactions: A General Introduction
  • 1.1.1 Magnetic Moments
  • 1.1.2 Zeeman Interaction
  • 1.1.3 Internal NMR Spin Interactions
  • 1.2 Paramagnetic Interactions in NMR
  • 1.2.1 Magnetic Interactions in Battery Materials
  • 1.2.2 Hyperfine Interactions in NMR
  • 1.3 Calculating Paramagnetic NMR Parameters
  • 1.3.1 NMR Shifts of Paramagnetic Molecules.
  • 1.3.2 NMR Shifts of Paramagnetic Battery Materials
  • References
  • Chapter 2 The Methodology of Electrochemical In Situ NMR and MRI
  • 2.1 Design and General Considerations of In Situ NMR
  • 2.1.1 Ex Situ Versus In Situ NMR
  • 2.1.2 Electrochemical Cells for In Situ NMR Characterization
  • 2.2 In Situ Magnetic Resonance Imaging
  • 2.2.1 MRI: Concepts and Limitations
  • 2.2.2 MRI of Electrochemical Processes and Model Systems
  • 2.2.3 Commercial Cells
  • 2.3 Conclusions
  • Acknowledgements
  • References
  • Chapter 3 Dealing with Quadrupolar Nuclei in Paramagnetic Systems.
  • 3.1 Quadrupole Interactions in Paramagnetic Systems
  • 3.2 Static Quadrupolar Spectra
  • 3.3 MAS Spectra
  • 3.4 High-resolution Methods for Half-integer Quadrupolar Nuclei: MQMAS and STMAS
  • 3.4.1 MQMAS
  • 3.4.2 STMAS
  • 3.5 Through-bond Correlations
  • 3.6 Through-space Correlations and Distance Measurements
  • 3.6.1 Cross-polarization
  • 3.6.2 D-HMQC
  • 3.6.3 D-RINEPT and PRESTO
  • 3.6.4 RESPDOR
  • 3.7 Conclusion and Outlook
  • Acknowledgements
  • References
  • Chapter 4 Dynamic Nuclear Polarisation Enhanced NMR
  • 4.1 Introduction
  • 4.2 Brief History of DNP.
  • 4.3 DNP Polarisation Transfer Mechanisms
  • 4.3.1 Solid Effect
  • 4.3.2 Cross Effect
  • 4.3.3 Overhauser Effect
  • 4.4 Experimental Consideration
  • 4.4.1 DNP Instrumentation
  • 4.4.2 Polarising Agents
  • 4.4.3 Sample Preparation
  • 4.4.4 Measuring Signal Enhancement Obtained by DNP
  • 4.5 Conclusion
  • Acknowledgements
  • References
  • Part II Case studies of electrochemical energy materials and devices
  • Chapter 5 Oxide-based Cathode Materials for Li- and Na-ion Batteries
  • 5.1 Introduction
  • 5.2 Lithium Layered Cathode Materials
  • 5.2.1 Lithium Cobalt Oxides.
  • 5.2.2 Lithium-containing Ternary Oxides
  • 5.2.3 Li-excess Layered Oxides
  • 5.2.4 Spinel Oxides
  • 5.3 Sodium Layered Cathode Materials
  • 5.4 Concluding Remarks
  • Acknowledgements
  • References
  • Chapter 6 NMR Studies on Polyanion-type Cathode Materials for LIBs/NIBs
  • 6.1 Iron-based Polyanions
  • 6.1.1 PO4 Series
  • 6.1.2 P2O7 Series
  • 6.1.3 PO4F Series
  • 6.1.4 SiO4 Series
  • 6.2 Manganese-based Polyanions
  • 6.2.1 PO4 Series
  • 6.2.2 P2O7 Series
  • 6.2.3 PO4CO3 Series
  • 6.2.4 SiO4 Series
  • 6.3 Cobalt-based Polyanions
  • 6.3.1 PO4 Series
  • 6.3.2 SiO4 Series.

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