Organic chemistry : concepts and applications / Allan D. Headley.
Provides an in-depth study of organic compounds that bridges the gap between general and organic chemistry Organic Chemistry: Concepts and Applications presents a comprehensive review of organic compounds that is appropriate for a two-semester sophomore organic chemistry course. The text covers the...
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| Format: | eBook |
| Language: | English |
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Hoboken, NJ :
John Wiley & Sons, Inc.,
2020.
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| Subjects: |
MARC
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| 100 | 1 | |a Headley, Allan D., |d 1955- |e author. |0 http://id.loc.gov/authorities/names/n2019020549. | |
| 245 | 1 | 0 | |a Organic chemistry : |b concepts and applications / |c Allan D. Headley. |
| 264 | 1 | |a Hoboken, NJ : |b John Wiley & Sons, Inc., |c 2020. | |
| 264 | 4 | |c ©2020. | |
| 300 | |a 1 online resource (xxiii, 594 pages) | ||
| 336 | |a text |b txt |2 rdacontent. | ||
| 337 | |a computer |b c |2 rdamedia. | ||
| 338 | |a online resource |b cr |2 rdacarrier. | ||
| 504 | |a Includes bibliographical references and index. | ||
| 505 | 0 | |a <P>Preface xvii</p> <p>About the Campanion Website xxiii</p> <p><b>1 Bonding and Structure of Organic Compounds 1</b></p> <p>1.1 Introduction 1</p> <p>1.2 Electronic Structure of Atoms 4</p> <p>1.3 Chemical Bonds 9</p> <p>1.4 Chemical Formulas 18</p> <p>1.5 The Covalent Bond 20</p> <p>1.6 Bonding- Concept Summary and Applications 28</p> <p>1.7 Intermolecular Attractions 29</p> <p>1.8 Intermolecular Molecular Interactions -- Concept Summary and Applications 31</p> <p>End of Chapter Problems 34</p> <p><b>2 Carbon Functional Groups and Organic Nomenclature 39</b></p> <p>2.1 Introduction 39</p> <p>2.2 Functional Groups 39</p> <p>2.3 Saturated Hydrocarbons 41</p> <p>2.4 Organic Nomenclature 45</p> <p>2.5 Structure and Nomenclature of Alkanes 45</p> <p>2.6 Unsaturated Hydrocarbons 54</p> <p>2.7 Structure and Nomenclature of Alkenes 56</p> <p>2.8 Structure and Nomenclature of Substituted Benzenes 58</p> <p>2.9 Structure and Nomenclature of Alkynes 60</p> <p>End of Chapter Problems 61</p> <p><b>3 Heteroatomic Functional Groups and Organic Nomenclature 63</b></p> <p>3.1 Properties and Structure of Alcohols, Phenols, and Thiols 63</p> <p>3.2 Nomenclature of Alcohols 66</p> <p>3.3 Nomenclature of Thiols 68</p> <p>3.4 Structure and Properties of Aldehydes and Ketones 69</p> <p>3.5 Nomenclature of Aldehydes 70</p> <p>3.6 Nomenclature of Ketones 71</p> <p>3.7 Structure and Properties of Carboxylic Acids 73</p> <p>3.8 Nomenclature of Carboxylic Acids 75</p> <p>3.9 Structure and Properties of Esters 78</p> <p>3.10 Structure and Properties of Acid Chlorides 82</p> <p>3.11 Structure and Properties of Anhydrides 83</p> <p>3.12 Structure and Properties of Amines 84</p> <p>3.13 Structure and Properties of Amides 88</p> <p>3.14 Structure and Properties of Nitriles 90</p> <p>3.15 Structure and Properties of Ethers 91</p> <p>3.16 An Overview of Spectroscopy and the Relationship to Functional Groups 94</p> <p><b>4 Alkanes, Cycloalkanes, and Alkenes: Isomers, Conformations, and Stabilities 103</b></p> <p>4.1 Introduction 103</p> <p>4.2 Structural Isomers 103</p> <p>4.3 Conformational Isomers of Alkanes 104</p> <p>4.4 Conformational Isomers of Cycloalkanes 108</p> <p>4.5 Geometric Isomers 114</p> <p>4.6 Stability of Alkanes 119</p> <p>4.7 Stability of Alkenes 121</p> <p>4.8 Stability of Alkynes 122</p> <p>End of Chapter Problems 123</p> <p><b>5 Stereochemistry 125</b></p> <p>5.1 Introduction 125</p> <p>5.2 Chiral Stereoisomers 126</p> <p>5.3 Significance of Chirality 129</p> <p>5.4 Nomenclature of the Absolute Configuration of Chiral Molecules 131</p> <p>5.5 Properties of Stereogenic Compounds 133</p> <p>5.6 Compounds with More Than One Stereogenic Carbon 134</p> <p>5.7 Resolution of Enantiomers 137</p> <p>End of Chapter Problems 140</p> <p><b>6 An Overview of the Reactions of Organic Chemistry 145</b></p> <p>6.1 Introduction 145</p> <p>6.2 Acid-Base Reactions 145</p> <p>6.3 Addition Reactions 149</p> <p>6.4 Reduction Reactions 150</p> <p>6.5 Oxidation Reactions 153</p> <p>6.6 Elimination Reactions 154</p> <p>6.7 Substitution Reactions 156</p> <p>6.8 Pericyclic Reactions 158</p> <p>6.9 Catalytic Coupling Reactions 158</p> <p>End of Chapter Problems 159</p> <p><b>7 Acid-Base Reactions in Organic Chemistry 165</b></p> <p>7.1 Introduction 165</p> <p>7.2 Lewis Acids and Bases 165</p> <p>7.3 Relative Strengths of Acids and Conjugate Bases 166</p> <p>7.4 Predicting the Relative Strengths of Acids and Bases 169</p> <p>7.5 Factors That Affect Acid and Base Strengths 170</p> <p>7.6 Applications of Acid-Bases Reactions in Organic Chemistry 176</p> <p>End of Chapter Problems 180</p> <p><b>8 Addition Reactions Involving Alkenes and Alkynes 183</b></p> <p>8.1 Introduction 183</p> <p>8.2 The Mechanism for Addition Reactions Involving Alkenes 183</p> <p>8.3 Addition of Hydrogen Halide to Alkenes (Hydrohalogenation of Alkenes) 185</p> <p>8.4 Addition of Halogens to Alkenes (Halogenation of Alkenes) 196</p> <p>8.5 Addition of Halogens and Water to Alkenes (Halohydrin Formation) 198</p> <p>8.6 Addition of Water to Alkenes (Hydration of Alkenes) 199</p> <p>8.7 Addition of Carbenes to Alkenes 207</p> <p>8.8 The Mechanism for Addition Reactions Involving Alkynes 209</p> <p>8.9 Applications of Addition Reactions to Synthesis 213</p> <p>End of Chapter Problems 214</p> <p><b>9 Addition Reactions Involving Carbonyls and Nitriles 223</b></p> <p>9.1 Introduction 223</p> <p>9.2 Mechanism for Addition Reactions Involving Carbonyl Compounds 223</p> <p>9.3 Addition of HCN to Carbonyl Compounds 224</p> <p>9.4 Addition of Water to Carbonyl Compounds 226</p> <p>9.5 Addition of Alcohols to Carbonyl Compounds 230</p> <p>9.6 Addition of Ylides to Carbonyl Compounds (The Wittig Reaction) 235</p> <p>9.7 Addition of Enolates to Carbonyl Compounds 237</p> <p>9.8 Addition of Amines to Carbonyl Compounds 240</p> <p>9.9 Mechanism for Addition Reactions Involving Imines 241</p> <p>9.10 Mechanism for Addition Reactions Involving Nitriles 242</p> <p>9.11 Applications of Addition Reactions to Synthesis 244</p> <p>End of Chapter Problems 246</p> <p><b>10 Reduction Reactions in Organic Chemistry 251</b></p> <p>10.1 Introduction 251</p> <p>10.2 Reducing Agents of Organic Chemistry 252</p> <p>10.3 Reduction of C=O and C=S Containing Compounds 255</p> <p>10.4 Reduction of Imines 263</p> <p>10.5 Reduction of Oxiranes 266</p> <p>10.6 Reduction of Aromatic Compounds, Alkynes, and Alkenes 268</p> <p>End of Chapter Problems 272</p> <p><b>11 Oxidation Reactions in Organic Chemistry 275</b></p> <p>11.1 Introduction 275</p> <p>11.2 Oxidation 275</p> <p>11.3 Oxidation of Alcohols and Aldehydes 279</p> <p>11.4 Oxidation of Alkenes Without Bond Cleavage 288</p> <p>11.5 Oxidation of Alkenes with Bond Cleavage 293</p> <p>11.6 Applications of Oxidation Reactions of Alkenes 296</p> <p>11.7 Oxidation of Alkynes 299</p> <p>11.8 Oxidation of Aromatic Compounds 300</p> <p>11.9 Autooxidation of Ethers and Alkenes 301</p> <p>11.10 Applications of Oxidation Reactions to Synthesis 302</p> <p>End of Chapter Problems 304</p> <p><b>12 Elimination Reactions of Organic Chemistry 309</b></p> <p>12.1 Introduction 309</p> <p>12.2 Mechanisms of Elimination Reactions 309</p> <p>12.3 Elimination of Hydrogen and Halide (Dehydrohalogenation) 316</p> <p>12.4 Elimination of Water (Dehydration) 319</p> <p>12.5 Applications of Elimination Reactions to Synthesis 323</p> <p>End of Chapter Problems 326</p> <p><b>13 Spectroscopy Revisited, A More Detailed Examination 331</b></p> <p>13.1 Introduction 331</p> <p>13.2 The Electromagnetic Spectrum 331</p> <p>13.3 UV-Vis Spectroscopy and Conjugated Systems 334</p> <p>13.4 Infrared Spectroscopy 337</p> <p>13.5 Mass Spectrometry 343</p> <p>13.6 Nuclear Magnetic Resonance (NMR) Spectroscopy 346</p> <p>End of Chapter Problems 367</p> <p><b>14 Free Radical Substitution Reactions Involving Alkanes 369</b></p> <p>14.1 Introduction 369</p> <p>14.2 Types of Alkanes and Alkyl Halides 371</p> <p>14.3 Chlorination of Alkanes 376</p> <p>14.4 Bromination of Alkanes 380</p> <p>14.5 Applications of Free Radical Substitution Reactions 386</p> <p>14.6 Free Radical Inhibitors 388</p> <p>14.7 Environmental Impact of Organohalides and Free Radicals 389</p> <p>End of Chapter Problems 391</p> <p><b>15 Nucleophilic Substitution Reactions at sp<sup>3</sup> Carbons 393</b></p> <p>15.1 Introduction 393</p> <p>15.2 The Electrophile 393</p> <p>15.3 The Leaving Group 394</p> <p>15.4 The Nucleophile 397</p> <p>15.5 Nucleophilic Substitution Reactions 397</p> <p>15.6 Bimolecular Substitution Reaction Mechanism (S<sub>N</sub>2 Mechanism) 400</p> <p>15.7 Unimolecular Substitution Reaction Mechanism (S<sub>N</sub>1 Mechanism) 406</p> <p>15.8 Applications of Nucleophilic Substitution Reactions -- Synthesis 414</p> <p>End of Chapter Problems 420</p> <p><b>16 Nucleophilic Substitution Reactions at Acyl Carbons 425</b></p> <p>16.1 Intr. | |
| 520 | |a Provides an in-depth study of organic compounds that bridges the gap between general and organic chemistry Organic Chemistry: Concepts and Applications presents a comprehensive review of organic compounds that is appropriate for a two-semester sophomore organic chemistry course. The text covers the fundamental concepts needed to understand organic chemistry and clearly shows how to apply the concepts of organic chemistry to problem-solving. In addition, the book highlights the relevance of organic chemistry to the environment, industry, and biological and medical sciences. The author includes multiple-choice questions similar to aptitude exams for professional schools, including the Medical College Admissions Test (MCAT) and Dental Aptitude Test (DAT) to help in the preparation for these important exams. Rather than categorize content information by functional groups, which often stresses memorization, this textbook instead divides the information into reaction types. This approach bridges the gap between general and organic chemistry and helps students develop a better understanding of the material. A manual of possible solutions for chapter problems for instructors and students is available in the supplementary websites. This important book: -''' Provides an in-depth study of organic compounds with division by reaction types that bridges the gap between general and organic chemistry -''' Covers the concepts needed to understand organic chemistry and teaches how to apply them for problem-solving -''' Puts a focus on the relevance of organic chemistry to the environment, industry, and biological and medical sciences -''' Includes multiple choice questions similar to aptitude exams for professional schools' Written for students of organic chemistry, Organic Chemistry: Concepts and Applications is the comprehensive text that presents the material in clear terms and shows how to apply the concepts to problem solving. | ||
| 588 | 0 | |a Online resource; title from digital title page (viewed on December 23, 2019) | |
| 650 | 0 | |a Chemistry, Organic |v Textbooks. |0 http://id.loc.gov/authorities/subjects/sh2009118860. | |
| 650 | 7 | |a Chemistry, Organic. |2 fast |0 (OCoLC)fst00853501. | |
| 655 | 7 | |a Textbooks. |2 fast |0 (OCoLC)fst01423863. | |
| 776 | 0 | 8 | |i Print version: |a Headley, Allan D., 1955- |t Organic chemistry. |b First edition. |d Hoboken, NJ : Wiley, 2019 |z 9781119504580 |w (DLC) 2019018485. |
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