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035 |a (TOE)ost4752987 
035 |a (TOE)4752987 
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086 0 |a E 1.99:ornl-3298 
086 0 |a E 1.99:ornl-3298 
088 |a ornl-3298 
245 0 0 |a RECOVERY OF PuF$sub 6$ BY FLUORINATION OF FUSED FLUORIDE SALTS  |h [electronic resource] 
260 |a Oak Ridge, Tenn. :  |b Oak Ridge National Laboratory. ;  |a Oak Ridge, Tenn. :  |b distributed by the Office of Scientific and Technical Information, U.S. Department of Energy,  |c 1962. 
300 |a Pages: 15 :  |b digital, PDF file. 
336 |a text  |b txt  |2 rdacontent. 
337 |a computer  |b c  |2 rdamedia. 
338 |a online resource  |b cr  |2 rdacarrier. 
500 |a Published through SciTech Connect. 
500 |a 10/01/1962. 
500 |a "ornl-3298" 
500 |a Cathers, G.I.; Jolley, R.L. 
520 3 |a Fused salt fluorination tests were conducted at 600 deg C to determine the feasibility of recovering plutonium as PuF/sub 6/ in the fused salt-fluoride volatility process. Recoveries and material balances were good, although the initial plutonium concentration in 50-50 mole% NaF -- ZrF/sub 4/ or 3l-2445 mole% LiF-- NaF-- ZrF/sub 4/ salt was only 2 ppm. The volatilization reaction appeared to be approximately first-order with espect to the plutonium concentration in the salt. Results of absorption of the volatilization PuF/sub 6/ on beds of LiF, CaF/ sub 2/, or NaF indicate that this is a possible method of trapping the material in fluoride volatility processes, possibly separately from UF/sub 6/. (auth) 
536 |b W-7405-ENG-26. 
650 7 |a Adsorption.  |2 local. 
650 7 |a Calcium Fluorides.  |2 local. 
650 7 |a Efficiency.  |2 local. 
650 7 |a Evaporation.  |2 local. 
650 7 |a Fluorides.  |2 local. 
650 7 |a Fluorination.  |2 local. 
650 7 |a Fused Salts.  |2 local. 
650 7 |a High Temperature.  |2 local. 
650 7 |a Lithium Fluorides.  |2 local. 
650 7 |a Plutonium Fluorides.  |2 local. 
650 7 |a Radiochemistry.  |2 local. 
650 7 |a Recovery.  |2 local. 
650 7 |a Reprocessing.  |2 local. 
650 7 |a Separation Processes.  |2 local. 
650 7 |a Sodium Fluorides.  |2 local. 
650 7 |a Testing.  |2 local. 
650 7 |a Trace Amounts.  |2 local. 
650 7 |a Traps.  |2 local. 
650 7 |a Volatility.  |2 local. 
650 7 |a Waste Processing.  |2 local. 
650 7 |a Zirconium Fluorides.  |2 local. 
650 7 |a Chemistry.  |2 edbsc. 
710 2 |a Oak Ridge National Laboratory.  |4 res. 
710 1 |a United States.  |b Department of Energy.  |b Office of Scientific and Technical Information.  |4 dst. 
856 4 0 |u http://www.osti.gov/scitech/biblio/4752987  |z Online Access (via OSTI) 
907 |a .b10530119x  |b 03-09-23  |c 05-20-19 
998 |a web  |b 05-20-19  |c f  |d m   |e p  |f eng  |g    |h 0  |i 1 
956 |a Information bridge 
999 f f |i 69f7d870-5d22-546f-bd07-91a05c1b1a6f  |s 7ab15604-ed1c-51da-b620-2d472979070a 
952 f f |p Can circulate  |a University of Colorado Boulder  |b Online  |c Online  |d Online  |e E 1.99:ornl-3298  |h Superintendent of Documents classification  |i web  |n 1